CYCLOHEXANONE

Cyclohexanone is the organic compound with the formula (CH₂)₅CO. The molecule consists of six-carbon cyclic molecule with aketone functional group. This colorless oil has an odor reminiscent of peardrop sweets as well as acetone. Over time, samples assume a yellow color due to oxidation. Cyclohexanone is slightly soluble in water, but miscible with common organic solvents. Billions of kilograms are produced annually, mainly as a precursor to nylon.

Cyclohexanone is produced by the oxidation of cyclohexane in air, typically using cobalt catalysts:

C₆H₁₂ + O₂ → (CH₂)₅CO + H₂O

This process co-forms cyclohexanol, and this mixture, called "KA oil" for ketone-alcohol oil, is the main feedstock for the production ofadipic acid. The oxidation involves radicals and the intermediacy of the hydroperoxide C₆H₁₁O₂H. In some cases, purified cyclohexanol, obtained by hydration of cyclohexene, is the precursor. Alternatively, cyclohexanone can be produced by the partialhydrogenation of phenol:

C₆H₅OH + 2 H₂ → (CH₂)₅CO

This process can also be adjusted to favor the formation of cyclohexanol.

Most cyclohexane goes into the production of intermediates for nylon, which has a variety of common applications such as clothing, tents and carpets as well as thermoplastics. Cyclohexane is also used as a solvent in chemical and industrial processes and recently has been substituted for benzene in many applications.

Michael Thang

08164850242

Source : wikipidia

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